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1 article(s) from Gómez-Marín, Ana M.

Some reflections on the understanding of the oxygen reduction reaction at Pt(111)

Ana M. Gómez-Marín,
Ruben Rizo and
Juan M. Feliu

Beilstein J. Nanotechnol. 2013, 4, 956–967, doi:10.3762/bjnano.4.108

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Scheme 1: Reaction pathways proposed for the ORR given by Wroblowa et al. [1].

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Figure 1: Stable voltammetric profile of a well-ordered Pt(111) electrode at 50 mV·s⁻¹, at two upper potentia...

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Figure 2: Evolution of the voltammetric profile of a Pt(111) electrode in 0.5 M H₂SO₄ as the electrode is cyc...

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Figure 3: Oxygen reduction on a Pt(111) electrode in oxygen saturated 0.1 M HClO₄. (A): Cyclic voltammetric p...

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Scheme 2: Possible adlayer reactions.

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Scheme 3: Associative ORR mechanism.

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Scheme 4: Dissociative ORR mechanism.

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Figure 4: Potential free energy diagram for oxygen reduction over Pt(111), Pt(211), Pt(100) and Pt(110) at 0....

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Figure 5: Plot of the half-height potential, E_1/2, for the oxygen reduction as a function of the angle of the...

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Figure 6: Plot of the kinetic currents at 0.8 V, j_kin(0.8 V), for the oxygen reduction as a function of the a...

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Figure 7: (A) Cyclic voltammograms for the ORR on a hanging meniscus rotating disc (HMRD) Pt(111) electrode f...

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Figure 8: Cyclic voltammograms in the high potential region for the ORR on a HMRD Pt(111) electrode in oxygen...

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Scheme 5: Reduction and oxidation of hydrogen peroxide.

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Figure 9: Hydrogen peroxide reduction and oxidation reactions on Pt(111) in 0.1 M HClO₄ + 1 mM H₂O₂. (A) Cycl...

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Full Research Paper

Published 27 Dec 2013

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